There are growing discussions about which type of alcohol makes the best solvent for spirit varnish, shellac and subsequently French polish. The leading favorite seems to be straight grain alcohol or ethanol over denatured alcohol which is mostly wood alcohol [methanol]. This may only be relevant to the United States as other countries sell denatured alcohol which is ethanol with unpalatable instead of poisonous denaturing agents added. So that stuff will just make you puke instead of making you go blind and dying.
Everclear™ is a commercially available straight grain alcohol if you purchase the 190 proof. They do sell a 150 proof alcohol which will not work for thinning shellac, French polish or spirit varnish, as it contains too much water. So check the label carefully. It is not available in some states.
Here are some definitions:
Absolute alcohol [anhydrous alcohol] – is pure alcohol with less than 1% water and is 200 proof. Laboratory grade and not for human consumption [traces of benzene] but makes a great solvent.
Alcohol – C2H5H or C2H6O made from the distillation of grain, starch or sugar, is colorless, volatile, flammable liquid has an agreeable odor and burnt taste. Ethanol has a specific gravity of 0.789 – 0.81, a molecular weight of 46.0414, with a dielectric constant of 24.3 to 33 at 68° (F), is a solvent for many gums, resins, etc., lamp fuel that has a flash point of 55.4° F and boils at 172° F. Isopropyl alcohol contains water and should not be used as a solvent. Over time alcohol which has an affinity for water will absorb it and become useless. Alcohol is best stored in a tightly stoppered glass container.
Azeotrope – is a mixture of alcohol and water which cannot be separated by simple distillation resulting in a 190 proof [95% alcohol, 5% water].
Denatured alcohol – is ethanol alcohol made poisonous by the addition of methanol [wood alcohol], acetone, benzene and other nasty ingredients to keep people from drinking the stuff. You cannot remove the hazardous components by distillation, filtering through bread or stratification. In other countries the alcohol is made unpalatable rather than poisonous.
Ethanol – C2H6O is alcohol made from grains and is the safe form of alcohol with a specific gravity of 0.789 and a molecular weight of 46.0414. Ethanol has a flash point of 55.4° F and boils at 172° F. Ethanol is more viscous and less volatile than methanol.
Methyl alcohol – CH3OH [methanol, 1932] wood alcohol, is made from the distillation of wood {originally boxwood} and is extremely poisonous and used as a denaturing agent for ethanol. It has a specific gravity of 0.7913, a molecular weight of 32.04, a flash point of 54° F and a boiling point of 148.4° F. A sip of this stuff will make you go permanently blind and a shot [1 ounce] is fatal. Methanol is less viscous and more volatile than ethanol.
Proof – is the ratio of alcohol to water. Originally determined by putting alcohol on gunpowder, if it is at least 100 proof (50% alcohol), when ignited will ignite the gunpowder.
I for one like the fact that the pure straight grain alcohol is not going to kill me, unless I drink too much of it, nor make me ill by breathing the stuff. I tried using denatured alcohol in my alcohol torch [lamp] with a coil of platinum wire wrapped around the wick, which becomes incandescent when ignited. Worked great, very hot and when I accidently breathed in the fumes, I dropped to my knees. Nasty, nasty fumes. I switched over to pure grain alcohol and no nasties.
As for the difference as a solvent for spirit varnish, for the same reason, it smells good. As for a shellac thinner works about the same as near as I can tell, but does smell better. When it comes to French polish many people swear by pure grain alcohol, describing its ease of use and other descriptive terms like ‘buttery’ and ‘creamy’, etc., are applied. I like the stuff for French polish as well it seems to be smoother during application.
I am afraid I cannot tell after all has dried, which is which. The results appear to be the same, just a difference in ease of application. I am avoiding all of the problems by making my own grain alcohol, see here.
What do you think? Notice any difference?
Stephen























